Calculating corrosion rates

The corrosion rates are calculated from icorr (the corrosion current) multiplied by the Metal factor. The following formulas are used :

    mm/year corrosion rate = (Metal factor X icorr) ÷ 1000

    mils / year corrosion rate = (Metal factor X icorr) ÷ 25.4

where Icorr is calculated from:

    icorr (A/m² ) = (ba x bc) ÷ (2.3 X Rp X (ba + bc))

    ba is anodic Tafel slope in Volts

    bc is the cathodic Tafel slope in Volts

    Rp is the polarisation resistance in W /m²

The metal factor is calculated from:

    Metal factor = (t X K) ÷ r

    t (seconds in year) = 365.2422454 * 24 * 60 * 60 = 31556930 seconds

    r is the metal density in g/cm²

    K the electrochemical equivalent in g / coulombs K is obtained from

    K = (atomic % of element X atomic weight of element) ÷ (96487 X Valency of element)

Using the metal editor

The metal editor enables metal factors to be created from known compositions of metals or alloys the properties of the most popular metals and alloys are already included.

metal1.gif (11879 bytes)

Creating a new metal

If a metal is not listed it can be created the following illustration will create Brass 70/30. Firstly a new blank metal must be created this can be done by clicking on the metal2.gif (1129 bytes) button.

Next the name of the metal is typed and the Accept button is pressed:

metal3.gif (2560 bytes)

This new metal is then transferred onto the main page in amongst all the existing metals and is automatically highlighted. The Selected item section will have no entries. From this point there are two ways of setting the metal factor the first and easiest way is to just type the metal factor if it is known into the metal factor box. The second way is to build the metal up from its elements and then let the program calculate the metal factor. Brass 70/30 is composed of 70% Copper and 30% Zinc to add elements firstly start with the largest Cu. Click the matel4.gif (1067 bytes) button and the Element selection page will appear:

metal6.gif (19827 bytes)

Move the mouse over to element Cu (29). The Highlighted element section in the bottom left of the page will change to show the element parameters for Cu. Click the left mouse button to transfer all the element parameters to the Element settings section in the bottom right. There are two items which have to be checked first is Weight %. Initially when an element is selected the program calculates the remaining % needed to fill the metal. For the first element the weight % is set to 100 this value should be reduced to 70. The other item which requires attention is the Valency box. The most popular valencies for the selected element are shown in the Valency box. Copper has two typical valencies of 1 and 2. For the example of Brass a Valency of 1 is normally used. If a Valency is not listed then just type the number required into the Valency box. Before Finish is selected the settings for copper should resemble:

metal7.gif (2593 bytes)

Next 30% Zinc has to be added this is done in exactly the same way as for copper the Valency for Zinc is normally 2. The Selected item section on the main page should now resemble:

metal8.gif (4613 bytes)

Finally the metal density for Brass is set to 8550Kg/m>³ and when in the above example the metal9.gif (1008 bytes) button is pressed a Metal factor of 2083 is calculated.

Interestingly for selective corrosion such as dezincification the Valency of Cu should be set to 0.

The program is able to automatically suggest a density if there is only one element which is set to 100% composition.

Editing an existing metal

Existing metals can be edited by first choosing the metal. The element to be edited is selected and the Edit button clicked. On the Element page the settings can then be changed remember to re-click the Calculate button to get the new metal factor.

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